Blacken silver coins. What causes it?

towzilla

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My hunting buddy found a very nice Silver dollar today, It's posted on eye popping mind blowing. Beautiful silver dollar but it is blackened around the edges. What cause this. Different soil conditions, Wet ground, Chemicals. Any ideas. It just made me wonder so thought i'd throw it out there for discussion. I had found one last week and no discoloration at all. But have seen two this week that were. Both were found in places that no way could they have been counterfeit.
 
I understand that it's actually sulphur, not oxygen, that blackens silver.
 
Silver does not oxidize under normal circumstances - the black tarnish is caused by sulfide. In wet or swampy areas (saturated soil), bacteria in the soil will generate hydrogen sulfide which will react with silver. That's my understanding, though I'm not a chemist.
 
I wonder often at how bad my silver comes up, from saltwater. How they get so bad...
 

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Shipwreck silver is often oxidized to the point that a Riale looks like one half of an oreo cookie. Crack that open along the horixontal axis and inside is a shiny silver coin. Imwonder how many folks wandering along beaches in the Gulf found one of thes "flat round black rocks" and sent it skipping over thewater, counting the splashes? LOL
 
Shipwreck silver is often oxidized to the point that a Riale looks like one half of an oreo cookie. Crack that open along the horixontal axis and inside is a shiny silver coin. Imwonder how many folks wandering along beaches in the Gulf found one of thes "flat round black rocks" and sent it skipping over thewater, counting the splashes? LOL

Haha that made me laugh
 
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