i don't know if i'd do anything with it. i find those old dug thimbles to be extremely fragile as there's not a whole lot of metal there to begin with it. i've dug up bent ones and generally they don't survive trying to be straightened.
but i do agree with the peroxide. put a little bit in a shot glass, nuke it for 15 seconds and drop your thimble in there for 20-30 seconds and try giving it a VERY gentle cleaning with a toothbrush.
Pete